(η5-Cyclopentadienyl)(propionitrile-κN)bis(triphenylphosphine-κP)ruthenium(II) trifluoromethanesulfonate
نویسندگان
چکیده
The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru-P = 2.3585 (4) and 2.3312 (4) Å, and Ru-N = 2.0422 (15) Å as the legs. The CF(3)SO(3) (-) anion is anchored in the crystal lattice by C-H⋯O and C-H⋯F hydrogen bonds, with C⋯F,O distances starting at 3.125 (2) Å.
منابع مشابه
(Benzonitrile-κN)chlorido[hydridotris(pyrazol-1-yl-κN 2)borato](triphenylphosphine-κP)ruthenium(II) ethanol solvate. Corrigendum
The author list in the paper by Tong, Hung, Wang, Lin & Lo [Acta Cryst. (2009), E65, m438] is corrected.[This corrects the article DOI: 10.1107/S1600536809010265.].
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